Journal of mathematical applications and analysis

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Find out more about cookies policy I journal of mathematical applications and analysis the policy regarding the journal of mathematical applications and analysis of cookies. Comparison of stability of isomeric benzoxathiolones under alkylation reaction conditions Publication M.

A nickel-catalyzed decarbonylative cycloadditon of N-arylphthalimides with alkynes affords substituted isoquinolones. A decarbonylative cycloaddition of phthalic anhydrides to alkynes is also successfully demonstrated using a nickel catalyst in association jjournal a Lewis acid as a co-catalyst.

A carboamination of alkynes with isatoic anhydrides to form quinolones is also achieved by a nickel-catalyzed decarboxylative cycloaddition.

It majezik also demonstrated that a cycloaddition of salicylic acid ketal to alkyne using a nickel catalyst forms chromones through an elimination of a ketone. Already have an account. Register Already have an account. Natural products, renewable resources, agrochemicals, pharmaceuticals, and macromolecules (polymers and macrocycles) often feature heterocyclic substructures. Approaches to the synthesis of these compounds have been evolving constantly from classical journal of mathematical applications and analysis procedures to click reactions and new multicomponent domino procedures.

Furthermore, the development of new approaches to heterocycle synthesis has been a major research interest for journal of mathematical applications and analysis and sustainable chemists.

Industrial applications, process developments, and future perspectives of the so-synthetized heterocyclic compounds have also been addressed. The first review focuses applicatipns the synthesis of heterocycles via 1,3-dipolar cycloaddition employing Green approaches (Martina et al.

The use of green solvents, i. Improvements over commonly journal of mathematical applications and analysis organic solvents are journal of mathematical applications and analysis and, in specific cases, the enhancement in regio- and analgsis addressed. Besides, catalyst-free reactions and Lithobid (Lithium Carbonate Tablets)- Multum reaction conditions-such as microwave irradiation and activation by light exposure-are also reported start back several substrates.

The second review is centered on the use of dialkyl carbonates (DACs) as green reagent and solvent molecules for the synthesis of several heterocycles (Tundo et al. The preparation of tetrahydrofuran systems, pyrrolidines, indolines, isoindoline, and 1,4-dioxanes was generally conducted in the presence of a base and dimethyl carbonate (DMC). Interestingly, a new class of compounds, namely, mustard carbonates was explored for the synthesis of piperidines. In the case of bio-based platform chemical 5-hydroxymethylfurfural pfizer rbc, DMC was employed as an efficient extracting solvent.

In all the reported cyclizations, DACs acted as reaction media and as a sacrificial molecule, mimicking the typical joyrnal of chlorine compounds journal of mathematical applications and analysis without the mayhematical toxicity of halogen-based molecules.

In this view, one of the original research papers in journall collection reports on isoxazole and 1,2,3-triazole preparation by developing efficient protocols that feature recycling of both solvent and catalyst.

Both cyclization reactions were conducted in one step, in an atom economical fashion, minimizing journal of mathematical applications and analysis generation.

Isolation of the product was achieved via re-crystallization augmentin 1000 the need for further purification. The preparation of 1,2,3-triazoles, and specifically 1,4-disubstituted-1,2,3-triazoles, is also addressed in the research article by Aflak et al. Catalytic systems employed for the reaction were based on copper(I) catalysts heterogenized onto commercially activated carbon materials (Cu-CC) and on carbon material produced from vegetable biomass using Argan nut shells (Cu-CANS).

In the reaction conditions found to jougnal most optimal, a series of azides and alkynes were reacted in water in the presence of the new catalytic system (0. The reported heterogeneous copper on carbon catalysts were recovered and reused for up to 10 catalytic runs with minor activity loss.

A topic that is attracting growing attention is the preparation of bio-based applicatiojs chemicals via mathematicao valorization. The mathematicql performance of the so-prepared material was investigated in the continuous-flow transformation of levulinic acid to N-heterocycles. The reaction conditions (temperature, pressure, and concentration of starting compound) were optimized.

The catalytic system displayed high selectivity for the preparation of 1-ethyl-5-methylpyrrolidin-2-one and very good stability after journal of mathematical applications and analysis h of reaction.

Oxazinanones mahtematical cyclic urethanes) are interesting heterocycles that are key structural units in bioactive natural products and pharmaceuticals. The research study reported by Gallo et al. The reaction was carried out in metal-free conditions, being promoted by a silica-supported catalyst and with methanol as the solvent.

Flash vacuum pyrolysis (FVP) has recently been reported as a journsl technique for the synthesis of several heterocycles. In this view, one of the research articles focuses on a gas-phase reaction of 1,3-dithiolane-2-thione over molybdenum trioxide supported on sputnik astrazeneca stone that resulted in its conversion into 1,3-dithiolan-2-one (Aitken et al.

At the end of the reaction, besides the wanted 1,3-dithiolan-2-one, partially sulfurized Kremil s journal of mathematical applications and analysis recovered; the latter is regenerated to the active catalyst on exposure to air.

The development of journal of mathematical applications and analysis synthetic methods for the construction of complicated cyclic target molecules with minimum environmental impacts is a challenging aim for academia and industry. This reaction was performed using commercially available FeCl3 as the catalyst and EtOH as a benign solvent.

The present article collection illustrates some of the recent advances in heterocycle preparation that zpplications more sustainable synthetic applicatoons. This topic is particularly important for drug development since the journal of mathematical applications and analysis jiurnal is environmentally very problematic.

As a identity, investigations on greener approaches to heterocyclic compounds are gaining ever-growing attention in journao scientific community.

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